353-55-9Relevant academic research and scientific papers
Fluoride anion catalyzed halogen dance in polyhalomethanes
Sasson, Y.,Kitson, F.,Webster, O, W.
, p. 599 - 600 (2007/10/02)
Tetrabutylammonium fluoride catalyzes the exchange of halogens between tetrahalomethanes.The presence of small amounts of haloform is suspected to be a necessary co-catalyst.Key Words: tetrabutyl ammonium fluoride; tetrahalomethanes; halogen exchange in.
PREPARATION OF HALO-F-METHANES VIA POTASSIUM FLUORIDE-HALOGEN CLEAVAGE OF HALO-F-METHYLPHOSPHONIUM SALTS
Burton, D. J.,Shin-Ya, S.,Kesling, H.S.
, p. 89 - 98 (2007/10/02)
Treatment of halo-F-methylphosphonium salts with potassium fluoride and halogen (I2, Br2, ICl, IBr) gives modest yields of halo-F-methanes.This method of preparation augments the classical Hunsdiecker approach to these materials.
