70201-86-4

Upstream product

• 446-52-6 2-Fluorobenzaldehyde 
• 78619-09-7 1-vinylbenzene 3,4-oxide 
• 54669-43-1 potassium ethanethiolate 
• 53606-33-0 2-(ethylsulfanyl)benzenecarbaldehyde 
• 27200-84-6 methyl triphenylphosphonium bromide 

Relevant academic research and scientific papers

Reaction of Styrene 3,4-Oxide with Ethanediol and Dehydration to Ethylthiostyrenes

Styrene 3,4-oxide reacts with the nucleophile ethanediol, and the product is dehydrated to give three isomeric ethylthiostyrenes via the corresponding ethylthiovinylcyclohexadienols without formation of thiiranium ions as intermediates.

SULFUR CHELATED RUTHENIUM COMPOUNDS USEFUL AS OLEFIN METATHESIS CATALYSTS

Sulfur chelated ruthenium compounds represented by the following formula: wherein M indicates the ruthenium metal bound to a benzylidene carbon; R represents C1-C7 alkyl group or optionally substituted aryl; X1 and X2 each independently represent halogen; Y1 and Y2 each independently denote unsubstituted or alkyl-substituted phenyl; and Z independently represents hydrogen, electron withdrawing or electron donating substituent, with m being an integer from 1 to 4, and processes and compositions related thereto.