70303-01-4Relevant academic research and scientific papers
Reactions of areneselenenamides with alkenes in the presence of phosphorus(V) and sulfur(IV) oxyhalides. New synthesis of β-Haloalkyl Selenides
Antipin,Klak,Beloglazkina,Zyk
experimental part, p. 842 - 847 (2009/12/09)
A new procedure was proposed for activation of areneselenenamides with phosphorus(V) and sulfur (IV) oxyhalides. According to the 1H, 13C, and 31P NMR data, areneselenenamide reacts with phosphorus oxyhalide to form interm
PHENYLSELENENYL CHLORIDE IN ACETONITRILE-WATER; A HIGHLY CONVENIENT REAGENT FOR HYDROXYSELENATION OF OLEFINS AND PREPARATION OF CYCLIC ETHERS FROM DIENES
Toshimitsu, Akio,Aoai, Toshiaki,Owada, Hiroto,Uemura, Sakae,Okano, Masaya
, p. 5301 - 5306 (2007/10/02)
The reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyalkyl phenyl selenides in excellent yields, providing the most convenient method for hydroxyselenation of olefins so far reported.When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields.From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond.
Electrophilic cleavage of cyclopropanes. The areneselenenylation of tetracyclo2,7.04,6>heptane (quadricyclene)
Beaulieu, Pierre L.,Morisset, Veronique M.,Garratt, Dennis G.
, p. 1005 - 1013 (2007/10/02)
The reaction of benzeneselenyl chloride with tetracyclo 3.2.0.02,7.04,6 heptane (quadricyclene) yields, under conditions of kinetic control, adducts of both 1,3-and conjugative 1,6-addition, the latter being formed preferentially.Ele
Factors influencing the nature of seleniranium ions in selenenyl chloride additions to alkenes: the use of methanol as solvent
Garratt, Dennis G.,Kabo, Ann
, p. 1030 - 1041 (2007/10/02)
The reaction of benzeneselenenyl chloride with some simple alkylsubstituted acyclic and cyclic alkenes has been investigated using methanol as the solvent.Products of solvent-incorporation , β-methoxyalkyl phenyl selenides, are normally favoured over the
