70338-42-0Relevant academic research and scientific papers
Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis
Jang, Yoon Kyung,Magre, Marc,Rueping, Magnus
supporting information, p. 8349 - 8352 (2019/10/16)
The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).
Copper-catalyzed regio- and stereoselective intermolecular three-component oxyarylation of allenes
Itoh, Taisuke,Shimizu, Yohei,Kanai, Motomu
supporting information, p. 2736 - 2739 (2014/06/09)
A copper(II)-catalyzed intermolecular three-component oxyarylation of allenes using arylboronic acids as a carbon source and TEMPO as an oxygen source is described. The reaction proceeded under mild conditions with high regio- and stereoselectivity and functional group tolerance. A plausible reaction mechanism is proposed, involving carbocupration of allenes, homolysis of the intervening allylcopper(II), and a radical TEMPO trap.
Free-radical-initiated coupling reaction of alcohols and alkynes: Not co but C-C bond formation
Liu, Zhong-Quan,Sun, Liang,Wang, Jian-Guo,Han, Jie,Zhao, Yan-Kai,Zhou, Bo
supporting information; scheme or table, p. 1437 - 1439 (2009/09/07)
This work demonstrates an efficient method to prepare allylic alcohols via direct C-C bond formation using electron-rich alkynes and aliphatic alcohols initiated by tert-butyl hydroperoxide.
Chemoenzymatic dynamic kinetic resolution of allylic alcohols: A highly enantioselective route to acyloin acetates
Bogar, Krisztian,Vidal, Pilar Hoyos,Alcantara Leon, Andres R.,Baeckvall, Jan-E.
, p. 3401 - 3404 (2008/02/12)
Dynamic kinetic resolution (DKR) of a series of sterically hindered allylic alcohols has been conducted with Candida antarctica lipase B (CALB) and ruthenium catalyst 1. The optically pure allylic acetates obtained were subjected to oxidative cleavage to
