70367-75-8Relevant academic research and scientific papers
THE NON-CHAIN RADICALOID C-ALKYLATION OF NITRONATE ANIONS: FURTHER EVIDENCE FOR THE MECHANISM
Katritzky, Alan R.,Chen, Jen-Luan,Marson, Charles M.,Maia, Angalamaria,Kashmiri, M. Akram
, p. 101 - 108 (2007/10/02)
The effects of the variation of solvent, pyridinium leaving group, N-substituent, and nitronate nucleophile have been studied in the C-alkylation of nitronate anions.These variations and studies of the effects of inhibitors, attempted entrainment reactions, and ESR work are all in accord with our previously suggested mechanism.
Kinetics and Mechanism of the C-Alkylation of Nitroalkane Anions by 1-Alkyl-2,4,6-triphenylpyridiniums: A Nonchain Reaction with Radicaloid Characteristics
Katritzky, Alan R.,Kashmiri, M. Akram,Ville, George Z. de,Patel, Ranjan C.
, p. 90 - 96 (2007/10/02)
The C-alkylation of 2-nitropropanide by N-substituted pyridiniums is first order in each reactant in Me2SO.The effect on the rate of temperature , N substituent, leaving group, and nucleophile was studied quantitatively.Overall, the evidence excludes an SN2 displacement and suggests that the reactions proceed by a free radical nonchain mechanism.
NUCLEOPHILIC SUBSTITUTION IN ORGANOMERCURY HALIDES BY A FREE RADICAL CHAIN PROCESS
Russel, Glen A.,Hershberger, James,Owens, Karen
, p. 43 - 56 (2007/10/02)
Primary and secondary alkylmercury halides react with the salts of secondary nitroalkanes to afford tertiary nitroalkanes, mercury metal, and halide ion.The reaction is light initiated and is strongly inhibited by radical scavengers.Cyclized products resu
