70372-37-1Relevant academic research and scientific papers
Hypervalent iodine chemistry: Novel and direct thiocyanation of alkenes using [bis(acetoxy)iodo]benzene/trimethylsilyl isothiocyanate reagent combination. Synthesis of 1,2-dithiocyanates
Bruno, Moira,Margarita, Roberto,Parlanti, Luca,Piancatelli, Giovanni,Trifoni, Maila
, p. 3847 - 3848 (1998)
Novel and direct thiocyanation of alkenes using [bis(acetoxy)iodo]benzene/trimethylsilyl isothiocyanate reagent combination has been developed.
Copper-catalyzed efficient dithiocyanation of styrenes: Synthesis of dithiocyanates
Lv, Yunhe,Pu, Weiya,Cui, Hao,He, Jialin,Zhang, Qinmei
supporting information, p. 1223 - 1229 (2016/08/05)
A novel Cu-catalyzed intermolecular chemoselectivity dithiocyanation of styrenes with ammonium thiocyanate has been developed under mild conditions. This reaction exhibits a wide range of functional-group tolerance in styrenes to afford various dithiocyanates. The reaction mechanism was primarily investigated and a radical process was proposed.
Cis-1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate as an efficient reagent for the synthesis of phenacyl thiocyanates and phenacyl azides
Badri, Rashid,Gorjizadeh, Maryam
experimental part, p. 2058 - 2066 (2012/06/04)
Styrenes efficiently undergo thiocyanation and azidation with cis-1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate at 0C to furnish the corresponding thiocyanatoketones and azidoketones. This method is a direct, one-pot synthesis under mild condition using methanol as solvent.
Ferric(III) chloride-promoted efficient thiocyanation of arylalkenes: A facile synthesis of dithiocyanates
Yadav,Reddy,Gupta, Manoj Kumar
, p. 1983 - 1986 (2007/10/03)
Anhydrous FeCl3 oxidizes potassium thiocyanate to the corresponding radical and promotes subsequent addition to nucleophilic olefins to produce dithiocyanate derivatives under mild conditions with high efficiency. Excellent yields and chemosele
A very efficient Cerium (IV) ammonium nitrate (CAN) mediated thiocyanation of aralkenes: Formation of dithiocyanates
Nair, Vijay,Nair, Latha G.
, p. 4585 - 4586 (2007/10/03)
A facile dithiocyanation of aralkenes mediated by Cerium (IV) ammonium nitrate is described.
Radical additions to olefins in the presence of iodobenzenediacetate: An easy route to alkyl dithiocyanates
De Mico, Antonella,Margarita, Roberto,Mariani, Andrea,Piancatelli, Giovanni
, p. 1889 - 1892 (2007/10/03)
We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO4)2 or TEMPO.
