704-59-6

Basic information

• Product Name: trans-4-methylbicyclo<4.4.0>decan-3-one
• CAS NO: 704-59-6
• Molecular Weight: 166.263
• Mol File: 704-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-4-methylbicyclo<4.4.0>decan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: trans-4-methylbicyclo<4.4.0>decan-3-one(704-59-6)
• EPA Substance Registry System: trans-4-methylbicyclo<4.4.0>decan-3-one(704-59-6)

Safety Data

• Hazardous Substances Data: 704-59-6(Hazardous Substances Data)

Upstream product

• 2001-50-5 trans-2,3-octalin 
• 917-54-4 methyllithium 
• 91971-50-5 (+/-)-4-Carboxy-trans-decalin-dion-(1,3) 
• 93306-65-1 (+/-)-2-Methyl-trans-decalindion-(1,3) 
• 63055-15-2 trans-decaline-1,3-dione 
• 109970-17-4 (+/-)-2,4-dioxo-(4arH.8acH)-decahydro-naphthoic acid-(1ξ)-ethyl ester 
• 4832-17-1 trans-decalin-2-one 
• 40434-59-1 methyl-4 bicyclo<4.4.0>decene-3,4 trans 
• 21399-51-9 epoxy-3,4 bicyclo<4,4,0>decane trans 
• 92188-27-7 3-methylbicyclo<4.4.0>dec-3-ene 
• 92057-76-6 (+/-)-2-Methyl-(4ar,8at)-decahydro-[2=x]naphthol 
• 92904-27-3 (+/-)-2-Methyl-3-methoxy-trans-Δ²-octalon-1 
• 17405-99-1 methyl-4e bicyclo<4.4.0>decanol-3e trans 
• 21399-51-9 (+/-)-2,3-epoxy-(4ar,8at)-decahydro-naphthalene 

Downstream Products

• 704-59-6 3e-Methyl-trans-decal-2-on 
• 13553-40-7 cis-2,2'-(cyclohexane-1,2-diyl)diacetic acid 
• 906-27-4 (+/-)-3t-methyl-(4ar.8at)-octahydro-naphthalen-2-one-(2,4-dinitro-phenylhydrazone) 

Relevant articles and documents

Thermal valence isomerization of cis-fused bicyclic cyclobutenes. A study of orbital symmetry control

This study shows that thermally promoted valence isomerizations of cis-fused bicyclic cyclobutenes, when free of steric constraint, yield products arising from both orbital symmetry allowed conrotatory openings of the labile σ bond in the cyclobutene ring. In the case of the related vinylcyclobutenes, one conrotatory mode produces a stable cis,trans,cis monocyclic triene whereas fission in the other allowed sense affords a thermally labile trans,cis,cis monocyclic triene which, in turn, cyclizes to yield a cyclohexadiene derivative. The product distributions are evaluated in terms of secondary orbital interactions.