70470-06-3

Basic information

• Product Name: 1-(9-Methyl-9-azabicyclo[4.2.1]non-2-en-2-yl)-Ethanone
• Synonyms: 1-(9-Methyl-9-azabicyclo[4.2.1]non-2-en-2-yl)-Ethanone
• CAS NO: 70470-06-3
• Molecular Formula: C11H17NO
• Molecular Weight: 179.262
• Mol File: 70470-06-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(9-Methyl-9-azabicyclo[4.2.1]non-2-en-2-yl)-Ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(9-Methyl-9-azabicyclo[4.2.1]non-2-en-2-yl)-Ethanone(70470-06-3)
• EPA Substance Registry System: 1-(9-Methyl-9-azabicyclo[4.2.1]non-2-en-2-yl)-Ethanone(70470-06-3)

Safety Data

• Hazardous Substances Data: 70470-06-3(Hazardous Substances Data)

Upstream product

• 63989-32-2 1-N-Methylamino-9-methyl-9-azabicyclo<3.3.1>nonan 
• 23418-82-8 cis-1,5-cyclooctanediol 
• 37996-41-1 9-oxabicyclo[3.3.1]nonan-1-ol 
• 70423-78-8 9-methyl-9-azabicyclo[4.2.1]nonan-2-one 
• 56258-84-5 9-methyl-9-azabicyclo<3.3.1>nonan-1-ol 
• 100514-06-5 2-(1-cyano-1-ethylidene)-9-methyl-9-azabicyclo<4.2.1>nonane 
• 50-00-0 formaldehyd 
• 85514-42-7 anatoxin-a 

Relevant articles and documents

Synthesis of Anatoxin-a

A short efficient synthesis of (+/-)-anatoxin-a, the alkaloidal toxin from Anabaena flos-aquae, is described.Bromination of 9-methyl-9-azabicyclononan-1-ol (3b) provides the key intermediate 9-methyl-9-azabicyclononan-2-one (6).Reaction of 6 with diethyl (1-cyanoethyl)phosphonate gives 2-(1-cyano-1-ethylidene)-9-methyl-9-azabicyclononane (8).Oxygenation of 8, followed by reduction and hydrolysis, gives N-methylanatoxin-a (1b) which has been earlier converted into anatoxin-a.