70508-51-9Relevant academic research and scientific papers
The Synthesis and Chemistry of Formylphosphonate
Cairns, Jana,Dunne, Colm,Franczyk, Thaddeus S.,Hamilton, Robert,Hardacre, Christopher,Stern, Michael K.,Treacy, Alan,Walker, Brian J.
, p. 385 - 388 (2007/10/03)
New methods of synthesis and reactions of formylphosphonate have been investigated. Attempts to deprotect the corresponding diethyl acetal with Ti(IV) halides led instead to the formation of halo(ethoxy)methylphosphonates which undergo substitution reactions with a wide range of nucleophiles. The products of reactions of formylphosphonate with bifunctional nucleophiles are determined in most cases by Baldwin's Rules, while the imines derived from formylphosphonate undergo Diels-Alder reactions only in those cases which carry a strongly electron-withdrawing N-substituent.
