70570-04-6Relevant articles and documents
Nitrosamines from N,N-Disubstituted Hydrazines
Boyer, Joseph H.,Krishnan, Ashwin M.
, p. 715 - 716 (1988)
Photolysis of nitro hydrazones (from N,N-disubstituted hydrazines and tetranitromethane) gave nitrosamines.
Nitrosamines and Hydrazones of Dinitroformaldehyde from N,N-Disubstituted Hydrazines, a Dialkyl Nitroxide, and Tetranitromethane
Krishnan, Ashwin M.,Wolford, Lionel T.,Boyer, Joseph H.
, p. 569 - 570 (2007/10/02)
N,N-Disubstituted hydrazines reacted with a mixture of a dialkylnitroxide and tetranitromethane to give nitrosamines and small amounts of hydrazones of dinitroformaldehyde.
Nitrosamines from N,N-Disubstituted Hydrazines Via Hydrazones of Dinitroformaldehyde and Ethyl Nitroglyoxylate
Boyer, Joseph H.,Krishnan, Ashwin M.
, p. 201 - 213 (2007/10/02)
N,N-Dialkyl, diaryl, and arylalkyl hydrazones of dinitroformaldehyde were obtained from hydrazines and either tetranitromethane (TNM) or iodotrinitromethane (ITM) and gave nitrosamines on irradiation at 350 nm in acetone for several days.Similar N,N-disubstituted hydrazones of ethyl nitroglyoxylate were obtained from the hydrazines and either ethyl dinitroiodoacetate (DNIA) or ethyl dinitrobromoacetate (DNBA) but were neither thermal nor photochemical precursors to nitrosamines, coproducts obtained in minor amounts.Explanations for the formations of the hydrazones and nitrosamines were offered.
