706-25-2Relevant academic research and scientific papers
Fluoroalkylselenolation of Alkyl Silanes/Trifluoroborates under Metal-Free Visible-Light Photoredox Catalysis
Ghiazza, Clément,Khrouz, Lhoussain,Billard, Thierry,Monnereau, Cyrille,Tlili, Anis
supporting information, p. 1559 - 1566 (2019/11/03)
Herein a metal-free fluoroalkylselenolation of alkylsilanes as well as potassium alkyltrifluoroborates under visible light photocatalysis is disclosed. The developed methodologies are performed under mild conditions, room temperature in the presence of an organic photocatalyst and blue LED irradiation. Mechanistic investigations including luminescence and EPR spectroscopy allow us to shed light on both mechanisms.
Palladium-catalyzed C(sp3)-C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes
Cai, Guilong,Huang, Yingda,Du, Tingting,Zhang, Shaowen,Yao, Bo,Li, Xiaofang
supporting information, p. 5425 - 5427 (2016/05/09)
The first C(sp3)-C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.
Catalysis of Kumada-Tamao-Corriu coupling by a (POC OP)Rh pincer complex
Timpa, Samuel D.,Fafard, Claudia M.,Herbert, David E.,Ozerov, Oleg V.
supporting information; experimental part, p. 5426 - 5429 (2011/06/27)
A pincer-based (POCOP)Rh catalyst is demonstrated to be an active and well-defined catalyst for the coupling of select aryl and alkyl Grignards with aryl iodides. The proposed intermediacy of oxidative addition of aryl halides to (POCOP)RhI is supported by the isolation of the oxidative addition product. The Royal Society of Chemistry.
Reactions of a N-acyliminium ion pool with benzylsilanes. Implication of a radical/cation/radical cation chain mechanism involving oxidative C-Si bond cleavage
Maruyama, Tomokazu,Mizuno, Yusuke,Shimizu, Ikuo,Suga, Seiji,Yoshida, Jun-Ichi
, p. 1902 - 1903 (2007/10/03)
The reaction of a N-acyliminium ion pool with benzylsilane proceeds by a chain mechanism involving oxidative C-Si bond cleavage. A radical/cation/radical cation crossover mechanism involving single electron transfer has been proposed. The effective binary
