70634-62-7Relevant articles and documents
Reactivity of Tetra-n-butylammonium Di-μ-chloro-bis. A General Method for the Synthesis of cis Isomers of Neutral and Anionic Palladium(II) Complexes
Uson, Rafael,Fornies, Juan,Espinet, Pablo,Martinez, Francisco,Tomas, Milagros
, p. 463 - 465 (2007/10/02)
The reaction of n4>2 with L (L = N, P, As, or Sb donor ligand) leads to the synthesis of novel anionic palladium complexes of the type n4>, which react with L to give the neutral complexes .Both families of compounds are the cis derivatives.Moreover, replacement of Cl by SCN or CN, and of L (SbPh3 or AsPh3) by PPh3, takes place without a change in configuration, giving again cis isomers.