70717-87-2

Upstream product

• 61199-73-3 methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside 
• 917-54-4 methyllithium 

Downstream Products

• 115957-13-6 1,5-anhydro-4-O-benzoyl-1,2,6-trideoxy-3-C-methyl-L-ribo-hex-1-enitol 
• 100017-87-6 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-L-erythro-hex-2-enopyranosid 
• 100017-89-8 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-β-L-erythro-hex-2-enopyranosid 
• 142895-19-0 C₄₇H₅₇IO₁₈S₃ 
• 142866-00-0 C₅₂H₇₁IO₁₉S₃Si 
• 1007221-63-7 (2S,3S,4R,5R,6R)-5-iodo-6-(4-methoxy-benzyloxy)-2,4-dimethyl-tetrahydropyran-3,4-diol 
• 1133161-63-3 benzyl 2,6-dideoxy-2-iodo-3-C-methyl-α-L-mannopyranoside 
• 1310721-45-9 (2R,3R,4S,5R,6S)-5-acetoxy-6-((2S,3S,4R,5R,6R)-6-(benzyloxy)-4-(tertbutyldimethylsilyloxy)-5-iodo-2,4-dimethyltetrahydro-2H-pyran-3-yloxy)-4-methoxy-2-methyltetrahydro-2H-pyran-3-yl benzoate 
• 1133161-30-4 (2S,3S,4R,5R,6R)-6-(benzyloxy)-4-(tert-butyldimethylsilyloxy)-5-iodo-2,4-dimethyltetrahydro-2H-pyran-3-ol 

Relevant academic research and scientific papers

Reactions of Acetals of L-Rhamnose with Lithium-organic Compounds. New Syntheses of Mycaral, Olivomycal, and Methyl 2,3,6-Trideoxy-α-L-erythro-hex-2-enopyranoside

Methyl α-L-mycaroside (6a) is obtained from the dideoxy-uloside 2 by Grignard addition.The benzylidene rhamnoside (1a) reacts with methyllithium to give in only one step mycaral (4) (21percent) and olivomycal (5) (72percent).With lithiumdiisopropylamide 1