61199-73-3

Basic information

• Product Name: methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside
• Synonyms: methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside
• CAS NO: 61199-73-3
• Molecular Weight: 266.294
• Mol File: 61199-73-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside(61199-73-3)
• EPA Substance Registry System: methyl 2,3-O-benzylidene-6-deoxy-α-L-mannopyranoside(61199-73-3)

Safety Data

• Hazardous Substances Data: 61199-73-3(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 14917-55-6 methyl 6-deoxy-α-L-mannopyranoside 

Downstream Products

• 129090-79-5 C₂₁H₁₉⁽²⁾HBr₂O₆ 
• 119824-72-5 C₂₁H₂₁⁽²⁾HO₆ 
• 108782-79-2 methyl 2,4-di-O-benzoyl-3,6-dideoxy-3-trichloroacetamido-α-L-altropyranoside 
• 108782-78-1 methyl 3-amino-2-O-benzoyl-3,6-dideoxy-α-L-altropyranoside 3N,4O-trichloroacetimidate 
• 23089-58-9 N-acetyl-L-ristosamine 
• 263327-90-8 methyl 2,3,6-trideoxy-3-C-methyl-4-O-(4-nitrobenzoyl)-α-L-threo-hex-2-enopyranoside 
• 37091-13-7 Methyl-4-O-benzoyl-3-(benzoylamino)-2,3,6-tridesoxy-3-C-methyl-α-L-lyxo-hexopyranosid 
• 1002757-17-6 methyl 2,3-O-benzylidene-6-deoxy-4-O-(methoxymethyl)-α-L-mannopyranoside 
• 1002757-16-5 methyl 2,3-O-benzylidene-6-deoxy-4-O-(2-methoxyethoxymethyl)-α-L-mannopyranoside 
• 53577-83-6 methyl endo-2,3-O-benzylidene-4-O-methyl-α-L-rhamnopyranoside 
• 108782-77-0 methyl 2,3-O-benzylidene-4-O-trichloroacetimidoyl-α-L-rhamnopyranoside 
• 105265-74-5 tert-Butyl-((3aR,4R,6S,7S,7aS)-4-methoxy-6-methyl-2-phenyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-dimethyl-silane 
• 64880-43-9 methyl 2-O-benzoyl-3-bromo-3,6-dideoxy-α-L-altropyranoside 
• 70717-87-2 1,5-anhydro-1,2,6-trideoxy-3-C-methyl-L-ribo-hex-1-enitol 

Relevant articles and documents

Synthesis of marmycin A and investigation into its cellular activity

Anthracyclines such as doxorubicin are used extensively in the treatment of cancers. Anthraquinone-related angucyclines also exhibit antiproliferative properties and have been proposed to operate via similar mechanisms, including direct genome targeting.

Dioxolanylium Ions Derived from Carbohydrates. XI. Aminosugar Formation by trans Opening with the Trichloroacetimidoyl Neighbouring Group

A variety of benzylidene sugars containing vicinal trichloroacetimidoyl groups have been oxidized by N-bromosuccinimide, to ascertain which structural features are necessary for neighbouring group participation from the iminoester in the opening of the transitory benzoxonium ion.The results indicate that the trichloroacetimidoyl group closely resembles the acyl group in its ability to participate, and that the resulting iminoester is strongly favoured compared to the benzoxonium ion.The outcome of the reaction in these cases is therefore a clean, regiospecific introduction of an amino group into the carbohydrate molecule.