70749-10-9

Upstream product

• 930-68-7 cyclohexenone 
• 106-99-0 buta-1,3-diene 
• 106-51-4 p-benzoquinone 

Downstream Products

• 111219-19-3 C₁₇H₂₂N₂O₂S 
• 84175-98-4 ethyl α-rel-(1S,3aS,5aS,6S,9aR)-6-<2-(tert-butyldiphenylsiloxy)ethyl>dodecahydropyrrolo<1,2-a>quinol-1-yl acetate 
• 84236-41-9 ethyl α-rel-(1R,3aS,5aS,6S,9aR)-6-<2-(tert-butyldiphenylsiloxy)ethyl>dodecahydropyrrolo<1,2-a>quinol-1-yl acetate 
• 80664-53-5 N--5-thiophenoxy-2-pyrrolidinone 
• 75685-48-2 (+/-)-gephyrotoxin 
• 84175-96-2 rel-(3aS,5aS,6S,9aR)-1(E)-(carbethoxymethylidene)-6-((2-tert-butyldiphenylsiloxy)ethyl)dodecahydropyrrolo<1,2-a>quinoline 
• 78392-02-6 2-quinol-1-yl>ethyl tert-butyldiphenylsilyl ether 
• 75685-52-8 1α,2,3,3aα,4,5,5aβ,6α,7,8,9,9aβ-dodecahydro-1-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-6-(2-hydroxyethyl)pyrrolo<1,2-a>quinoline 
• 78392-01-5 2-quinol-1-yl>ethyl tert-butyldiphenylsilyl ether 
• 78328-74-2 2-quinol-1-yl>ethyl tert-butyldiphenylsilyl ether 
• 78308-02-8 N-succinimide 
• 78308-03-9 N-succinimide 
• 78308-04-0 N--5-hydroxy-2-pyrrolidinone 
• 3849-23-8 3-bromo-trans-decalin-2-one 

Relevant academic research and scientific papers

Diels-Alder Reactions of Cycloalkenones. 1. Preparation and Structure of the Adducts

Uncatalyzed and aluminum chloride induced Diels-Alder reactions of 2-cyclopentenones, 2-cyclohexenones, and 2-cycloheptenones with 1,3-butadiene, isoprene, and (E)-piperylene are described.Structure analysis of the adducts and their hydrogenation products by standard means and 13C NMR spectroscopy is presented.

A Change from Kinetic to Thermodynamic Control Enables trans-Selective Stereochemical Editing of Vicinal Diols

Here, we report the selective, catalytic isomerization of cis-1,2-diols to trans-diequatorial-1,2-diols. The method employs triphenylsilanethiol (Ph3SiSH) as a catalyst and proceeds under mild conditions in the presence of a photoredox catalyst and under

A straightforward route to functionalized trans-diels-alder motifs

A sequence consisting of a Lewis acid-catalyzed Diels-Alder reaction on a 2-halocyclohexenone, followed by reductive alkylation, provides a route to trans-fused octalinones bearing angular methyl groups with functionality corresponding to that which would have been possible from a trans-directed Diels-Alder reaction.

Palladium-mediated transannular cyclizations of medium-ring olefinic enolsilanes

Medium-ring olefinic ketone and lactone enolsilanes were subjected to palladium(II)-mediated cycloalkenylation conditions. Diverse bicyclic ring products were obtained in moderate to good yields. The effect of olefin geometry and ring size is discussed.

Diels-Alder Reactions of Cycloalkenones. 12. Reaction of trans-Δ1,2-3-Octalone with (E)-Piperylene

The Diels-Alder reaction of (E)-piperylene with trans-Δ1,2-3-octalone under aluminum chloride catalysis is described and structure analysis of the adducts by NMR spectroscopy is presented.The diastereofacial selectivity of the reaction is discu

Enzymes in organic synthesis. 37. Preparation and characterization of potential decalindione substrates of horse liver alcohol dehydrogenase

The preparations of ten decalindiones for investigation as substrates of horse liver alcohol dehydrogenase are reported.The structure characterizations include clarifications of some ambiguities in the decalin literature.

Diels-Alder Reactions of Cycloalkenones. 3. Effects of Specific Reaction Parameters

The effects of the Lewis acid-ketone complexation time and temperature, the nature and amount of catalyst, and the concentrations of ketone and diene on the Diels-Alder reactions of 2-cyclopentenones, 2-cyclohexenones, and 2-cycloheptenones with 1,3-butadiene, isoprene, and (E)-piperylene are described.