70811-82-4

Basic information

• Product Name: (2S,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol
• Synonyms: (2S,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol
• CAS NO: 70811-82-4
• Molecular Weight: 291.39
• Mol File: 70811-82-4.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol(70811-82-4)
• EPA Substance Registry System: (2S,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol(70811-82-4)

Safety Data

• Hazardous Substances Data: 70811-82-4(Hazardous Substances Data)

Upstream product

• 51594-37-7 (4S,5S)-2-ethyl-4-hydroxymethyl-5-phenyl-2-oxazoline methyl ether 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 70811-83-5 (2R,3S)-2-((4S,5S)-4-Methoxymethyl-5-phenyl-4,5-dihydro-oxazol-2-yl)-4-methyl-pentan-3-ol 

Relevant articles and documents

STEREOSELECTIVITY IN THE ALDOL REACTION THE USE OF CHIRAL AND ACHIRAL OXAZOLINES AS THEIR BORON AZENOLATES

Chiral oxazolines, as their boron enolates derived from various boron triflates, react with aldehydes to give erythro-selectivity (97percent+percent) with enantiomeric purities of 50-60percent.Achiral oxazolines as their boron enolates derived from diisopinocamphenylborane give, on reaction with aldehydes, β-hydroxy esters with high threo-selectivity (90+percent) in 77-85percent ee.A variety of stucturally different oxazolines were also studied and many show high erythro-selectivity.