70813-86-4Relevant academic research and scientific papers
On the reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur and selenium) towards organyl halides for the synthesis of organyl phenyl chalcogenides
Peppe, Clovis,Borges De Castro, Lierson
experimental part, p. 678 - 683 (2009/10/30)
The reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur, selenium) towards organyl halides (organyl = alkyl, allyl, benzyl, acyl) was examined. A practical one-pot method to prepare organyl phenyl chalcogenides indium metal and diphenyl dichalcogenide was found. The coupling is fairly broad in scope and generally works better organyl halides capable to produce stable carbocations.
CARBOCYCLIC RING EXPANSION REACTIONS VIA RADICAL CHAIN PROCESSES
Baldwin, Jack E.,Adlington, Robert M.,Robertson, Jeremy
, p. 909 - 922 (2007/10/02)
A free radical mediated ring expansion of cis- and trans-α-alkylated-β-stannylcyclohexanones to provide efficient routes to cis- and trans-cyclononenones and cyclodecenones is described.The cis-/trans- relationship in the precursor was found to have signi
