70916-14-2Relevant academic research and scientific papers
Rhodium-catalyzed C-H activation of phenacyl ammonium salts assisted by an oxidizing C-N bond: A combination of experimental and theoretical studies
Yu, Songjie,Liu, Song,Lan, Yu,Wan, Boshun,Li, Xingwei
, p. 1623 - 1631 (2015/02/19)
Rh(III)-catalyzed C-H activation assisted by an oxidizing directing group has evolved to a mild and redox-economic strategy for the construction of heterocycles. Despite the success, these coupling systems are currently limited to cleavage of an oxidizing
Visible-light-induced Ci-S bond activation: Facile access to 1,4-diketones from β-ketosulfones
Xuan, Jun,Feng, Zhu-Jia,Chen, Jia-Rong,Lu, Liang-Qiu,Xiao, Wen-Jing
supporting information, p. 3045 - 3049 (2014/03/21)
A novel method for the synthesis of 1,4-diketones from β-ketosulfones was developed by means of a visible light-induced Ci￡S bond activation process. Symmetrical and unsymmetrical 1,4-diketones can be easily prepared in moderate to good yields. A new and efficient method for the synthesis of 1,4-diketones from β-ketosulfones was developed by means of a visible-light-induced Ci￡S bond activation process (see scheme). Symmetrical and unsymmetrical 1,4-diketones can be easily prepared in moderate to good yields.
NOVEL FLUORINATED ALKYLFLUOROPHOSPHORIC ACID SALT OF ONIUM AND TRANSITION METAL COMPLEX
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Page/Page column 21-22, (2010/11/25)
[Problems] To obtain a polymerization initiator (acid generating agent) having excellent power for initiation of cationic polymerization without containing arsenic or antimony. [Means for solution] Provided is a specific onium salt or transition metal complex salt of a fluorinated alkyl fluorophosphoric acid.
Effect of solvents on the reaction between phenacyl bromide and triethylamine
Pillay, M. Krishna,Nallu, M.
, p. 897 - 898 (2007/10/02)
Rate constants for the reaction of α-halogenocarbonyl compound such as phenacyl bromide with triethylamine in various solvents at 25 deg C, 30 deg C and 35 deg C have been determined.A plot of log k2 of BrCH2COPh+NEt reaction versus log k2
Effect of addition of phenols on the rate of Menschutkin reaction-Reaction between phenacyl bromide and triethylamine
Pillay, M. Krishna,Jeyaraman, R.,Nallu, M.
, p. 432 - 436 (2007/10/02)
Second order rate constants for the reaction between phenacyl bromide and triethylamine with and without phenols have been determined in aprotic solvents at 25 deg, 30 deg and 35 deg C.The addition of X-C6H4-OH (X=H, p-OCH3, p-CH3, p-Cl, p-Br and p-NO2) w
Quantitative Treatment of Reaction Rates in Functional Micelles and Comicelles
Bunton, Clifford A.,Hamed, Fareed H.,Romsted, Laurence S.
, p. 2103 - 2108 (2007/10/02)
Comicelles of dodecyldimethylammonium bromide (5) or N-phenylmyristohydroxamic acid (6) with cetyltrimethylammonium bromide (CTABr) are good dephosphorylating agents toward p-nitrophenyldiphenyl phosphate (p-NPDPP) at high p
