709655-01-6

Basic information

• Product Name: (2R,3R,4S,5R,6S,8R,9S)-8-allyl-9-allyloxy-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undecane
• Synonyms: (2R,3R,4S,5R,6S,8R,9S)-8-allyl-9-allyloxy-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undecane
• CAS NO: 709655-01-6
• Molecular Weight: 690.877
• Mol File: 709655-01-6.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R,4S,5R,6S,8R,9S)-8-allyl-9-allyloxy-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4S,5R,6S,8R,9S)-8-allyl-9-allyloxy-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undecane(709655-01-6)
• EPA Substance Registry System: (2R,3R,4S,5R,6S,8R,9S)-8-allyl-9-allyloxy-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undecane(709655-01-6)

Safety Data

• Hazardous Substances Data: 709655-01-6(Hazardous Substances Data)

Upstream product

• 213776-97-7 allyl (5,6,7,9-tetra-O-benzyl-1,2,3-trideoxy)-α-D-gluco-non-1-eno-4-ulopyranose 
• 213776-98-8 (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undec-9-ene 
• 213776-99-9 (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-2-benzyloxymethyl-1,7-dioxa-spiro[5.5]undec-8-ene 
• 776313-98-5 5,6,7,9-tetra-O-benzyl-1,2,3-trideoxy-D-gluco-non-1-eno-4-ulopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 

Relevant articles and documents

Synthesis and elaboration of functionalised carbohydrate-derived spiroketals

The scope of a stereoselective three-step approach for the synthesis of sugar derived spiroketals is presented. The methodology consists of Grignard addition of vinyl- or allylmagnesium bromide to a carbohydrate lactone, followed by K-10 clay mediated gly