70975-35-8

Upstream product

• 42787-33-7 S,S-Diphenyl-N-chlorosulfilimine 
• 22731-83-5 S,S-diphenylsulphoximine 
• 36744-90-8 S,S-Diphenylsulfilimine 
• 72277-48-6 diphenyl-N-<(2-chloro-3,3-dimethyl)butyl>sulphoximide 
• 70975-34-7 N-bromo-S,S-diphenyl sulfoximine 

Downstream Products

• 72277-53-3 C₁₇H₂₀ClNOS 
• 72277-48-6 diphenyl-N-<(2-chloro-3,3-dimethyl)butyl>sulphoximide 
• 72277-54-4 C₂₀H₂₆ClNOS 
• 72277-51-1 C₁₈H₂₀ClNOS 
• 22731-83-5 S,S-diphenylsulphoximine 
• 97383-39-6 S,S-diphenyl-N-(α-toluenesulfenyl)sulfoximine 
• 72277-51-1 diphenyl-N-(2-chlorocyclohexyl)sulphoximide 
• 70975-34-7 N-bromo-S,S-diphenyl sulfoximine 
• 72277-49-7 diphenyl-N-<(2-bromo-3,3-dimethyl)butyl>sulphoximide 
• 945-51-7 1,1'-sulfinylbisbenzene 

Relevant academic research and scientific papers

PREPARATION OF S,S-DIPHENYLSULFILIMINES, -SULFOXIMINES, AND -N-(P-TOLYLSULFONYL)SULFONEDIIMINES N-SUBSTITUTED WITH SULFUR GROUPS OF DIFFERENT OXIDATION STATES.

S,S-Diphenyl-N-(p-tolylthio)-, -N-(p-tolysulfinyl)-, -N-(p-toluenesulfinimidoyl-, -N-(p-tolsulfonyl)-, and -N-(p-toluenesulfonimidoyl)sulfoximines have been synthesized either by sulfenylation, sulfinylation, sulfinimidoylation, sulfonylation, and sulfoni

A CONVENIENT PREPARATION OF N-(ARENESULFONYL)SULFOXIMINES BY OXIDATION OF N-(ARENESULFONYL)SULFILIMINES WITH SODIUM HYPOCHLORITE IN A TWO PHASE SYSTEM

N-(Arenesulfonyl)sulfilimines can be oxidized to the corresponding sulfoximines in high yields with sodium hypochlorite in an AcOEt-H2O two phase system in the presence of quaternary ammonium salts as catalysts.

Homolytic Reaction of N-Halogenosulphoximides with Olefins and Toluene

Homolytic addition reaction of N-halogenosulphoximides, i.e. diphenyl-N-chlorosulphoximide (1), diphenyl-N-bromosulphoximide (2), and methylphenyl-N-chlorosulphoximide (3), to olefins such as t-butylethylene and cyclohexene under both u.v. irradiation and thermolysis in the presence of a radical initiator was found to afford the corresponding N-alkylated sulphoximides, which are presumed to be formed via the initial addition of the sulphoximidoyl radical.Meanwhile, homolytic bromination of toluene with N-bromosulphoximide (2) proceeded readily by u.v. irradiation, or by thermal reaction in the presence of a radical initiator, to afford benzyl bromide.However, chlorination of toluene was sluggish with N-chlorosulphoximides (1) and (3). α-Bromination was interpreted in terms of a chain process involving bromine molecules like the 'Goldfinger mechanism', but not via that involving the sulphoximidoyl radical.