97383-39-6Relevant academic research and scientific papers
h-BN@Copper(II) nanomaterial catalyzed cross-coupling reactions between sulfoximines and N-(phenylthio)-succinimide under mild condition
Lin, Yan,Guanghui,Liu, Yanzhao,Zheng, Yang,Nie, Ruifang,Guo, Li,Wu, Yong
, p. 68 - 73 (2018/05/23)
A novel and efficient method for the synthesis of N-S substituted sulfoximines has been established with h-BN-supported copper(II) nanomaterial as the catalyst. Catalyzed by this heterogeneous catalyst, the desired products were obtained with wide scope of substrates, good to excellent yields, free ligand and low-toxicity solvent. Moreover, after being reused ten times, there is almost no significant loss of its catalytic activity.
A One-Pot Cascade Reaction by Combining NH-Sulfoximines with Thiophenols Under Mild Conditions
Peng, Yao,Lin, Yan,Nie, Ruifang,Zheng, Yang,Liu, Yanzhao,Guo, Li,Wu, Yong
, p. 844 - 850 (2018/02/21)
A general protocol for the N-thioetherification of NH-sulfoximines has been developed. Catalyzed by [Cu(DMAP)4I]I, N-sulfenyl sulfoximines were synthesized by a one-pot cascade reaction with commercially available thiophenols as the sulfur sour
REACTION OF N-HALOSULFOXIMINES WITH DISULFIDES
Akasaka, T.,Furukawa, N.,Oae, S.
, p. 277 - 284 (2007/10/02)
The reaction of S,S-diphenyl-N-chloro-(1), S,S-diphenyl-N-bromo-(2), and S-methyl-S-phenyl-N-chlorosulfoximine (5) with disulfides in refluxing carbon tetrachloride was found to afford the corresponding sulfoxides.In the presence of pyridine, 1 and 2 reacted with disulfides at room temperature to give the corresponding bis-diphenylsulfoximinyl alkyl or aryl sulfonium halides arising from the reaction of the intermediary N-sulfenylated sulfoximine and the starting N-halosulfoximine.
