70983-17-4Relevant academic research and scientific papers
Infrared Spectra of Products Formed by the Photoinduced Reactions of (P2)x(O2)y Clusters in Solid Argon
McCluskey, Matthew,Andrews, Lester
, p. 2679 - 2687 (2007/10/02)
Infrared spectra of the photoinduced reaction of P2 and molecular oxygen in solid argon at 12 K have been recorded.Concentration studies showed that the products were derived from the photolysis of phosphorous-oxygen clusters, (P2)x(O2)y, where x = 1,2 an
Infrared Spectra of P4O6, P4O7, P4O8, P4O9, and P4O10 in Solid Argon
Mielke, Zofia,Andrews, Lester
, p. 2971 - 2976 (2007/10/02)
P4O6 was reacted with oxygen atoms (16O and 18O) obtained from ozone photolysis and discharge of oxygen.The P4O7-10 and P4O6(18)O1-4 products were trapped in solid argon and examined by infrared spectroscopy.The spectra of the four higher oxides support a central P4O6 cage structure with additional terminal P=16O or P=18O bonds.The P=16O and P=18O vibrations are identified in four higher oxides, and assignments are proposed for several of the more intense P4O6 cage absorptions.
