710313-10-3Relevant academic research and scientific papers
β-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten
Ignatov, Stanislav K.,Khalimon, Andrey Y.,Rees, Nicholas H.,Razuvaev, Alexei G.,Mountford, Philip,Nikonov, Georgii I.
, p. 9605 - 9622 (2009/12/25)
Reactions of bls(imldo) compounds (RN)2Mo(PMe3) n {n = 2, R = tBu; n = 3, R =2,6-dlmethylphenyl (Ar′) and 2,6-dlisopropylphenyl (Ar)) and (RN)2W(PMe 3)3 (R = 2,6-dimethylphenyl a
Unexpected features of stretched Si-H...Mo β-agostic interactions
Ignatov, Stanislav K.,Rees, Nicholas H.,Dubberley, Stuart R.,Razuvaev, Alexei G.,Mountford, Philip,Nikonov, Georgii I.
, p. 952 - 953 (2007/10/03)
Coupling of silanes with the imido group of (Ar′N) 2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between th
