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• 53001-06-2 2,2-diphenyl-4-pentenylamine 

Relevant academic research and scientific papers

Well-Defined β-Diketiminatocobalt(II) Complexes for Alkene Cyclohydroamination of Primary Amines

A well-defined low-coordinate β-diketiminatocobalt(II) alkyl complex is reported as an active precatalyst for the selective alkene cyclohydroamination of unprotected primary amines under mild conditions (rt-90 °C). The reaction mechanism has been investigated by deuterium-labeling, kinetics, and stoichiometric experiments and in-depth computational DFT studies. On the basis of these studies, we propose a stepwise noninsertive mechanism that features a rate-determining nucleophilic attack of the amido group of a monomeric cobalt(II) amidoalkene-aminoalkene adduct intermediate to the noncoordinated pendant alkene followed by a rapid proton transfer from the coordinated aminoalkene to the cyclized adduct.

Intramolecular hydroamination of aminoalkenes using rhodium(I) and Iridium(I) complexes with N,N-and P,N-donor ligands

Cationic rhodium(i) and iridium(i) complexes containing the bidentate heterocyclic N,N-donor ligand bis(1-pyrazolyl)methane (bpm) and the counterion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF-) were found to be efficient catalysts for the cycliz

Synthesis, characterization, and reactivity of aluminum alkyl/amide complexes supported by guanidinate and monoanionic OCO-pincer ligands

The synthesis and characterization of mixed alkyl/amide Al complexes supported by guanidinate and monoanionic OCO-pincer ligands are described. In situ generation of the lithium-guanidinate reagents via reaction of carbodiimides and lithium-amide reagents, followed by reaction with the corresponding AlMexCl3-x reagents, resulted in the formation of compounds 1-3. Subsequent reaction with lithium arylamide reagents provided access to mixed alkyl/amide-and bis-amide-substituted complexes 4-6, which were characterized by multinuclear NMR spectroscopy and elemental analysis. Single-crystal X-ray diffraction of compounds 5a and 6a confirmed the monomeric nature of these complexes and revealed the influence of the alkyl/amide functionalities on the bonding of the guanidinate ligands. A similar synthetic approach resulted in isolation of an OCO-pincer-supported Al dialkyl complex, which was also fully characterized. In contrast to the guanidinate compounds, complex 8 showed activity toward intramolecular hydroamination of 2,2-diphenylpent-4-en-1-amine.

Air-and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of RH and Ir

The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydr