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• 1076-43-3 benzene-d6 

Relevant academic research and scientific papers

Thermolysis of the benzene anion radical 18-crown-6 complex

The C-O and G-H bonds of 18-crown-6 are activated when 18-crown-6 is complexed with the potassium salt of the benzene anion radical. Evacuated glass bulbs containing the solid anion radical salt of potassium 18-crown-6 benzene anion radical were plunged into a bath at 320 C, resulting in mini-explosions and generating a series of compounds including dioxane, 2-methyl1,3-dioxolane, divinyl ether, hydrogen, methane, and 15-crown-5. Deuterium labeling studies proved that all of these compounds originated from the 18-crown-6. Further, these labeling studies were an aid in discerning the mechanism of the decomposition. Benzene, 1,4-cyclohexadiene, and cyclohexene were also generated. The last two originated from the reaction of the anion radical of benzene with hydrogen.

Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase

Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions we

A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C?H Bond Oxidation Reactions

S=2 oxoiron(IV) species act as reactive intermediates in the catalytic cycle of nonheme iron oxygenases. The few available synthetic S=2 FeIV=O complexes known to date are often limited to trigonal bipyramidal and very rarely to octahedral geom

Reactivity of 5,6-dihydro-5-hydroxythymid-6-yl-generated via photoinduced single electron transfer and the role of cyclohexa-1,4-diene in the photodeoxygenation process

The major reactive species formed via reaction of hydroxyl radical and the pyrimidine nucleoside thymidine, 5,6-dihydro-5-hydroxythymid-6-yl (1), is generated photochemically under anaerobic conditions from 6 via photoinduced single electron transfer. Und

Concerted and nonconcerted pathways for thermal conversions of deuterium-labeled cyclohexenes to butadienes and ethylenes

The retro Diels-Alder reactions of cyclohexene-3,3,6,6-d4 and the 4,5-cis isomers of cyclohexene-1,2,3,4,5,6-d6 have been followed using single-pulse shock tube kinetic and tunable diode laser infrared spectroscopic techniques. At te