71122-76-4

Basic information

• Product Name: 6-Chloro-2-phenyl-9β-(2',3',5'-tri-O-acetyl)-D-ribofuranosyl-purine
• Synonyms: 6-Chloro-2-phenyl-9β-(2',3',5'-tri-O-acetyl)-D-ribofuranosyl-purine
• CAS NO: 71122-76-4
• Molecular Weight: 488.884
• Mol File: 71122-76-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-Chloro-2-phenyl-9β-(2',3',5'-tri-O-acetyl)-D-ribofuranosyl-purine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Chloro-2-phenyl-9β-(2',3',5'-tri-O-acetyl)-D-ribofuranosyl-purine(71122-76-4)
• EPA Substance Registry System: 6-Chloro-2-phenyl-9β-(2',3',5'-tri-O-acetyl)-D-ribofuranosyl-purine(71122-76-4)

Safety Data

• Hazardous Substances Data: 71122-76-4(Hazardous Substances Data)

Upstream product

• 16321-99-6 2-amino-6-chloro-9-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)purine 
• 71-43-2 benzene 
• 5987-76-8 6-chloro-2-iodo-9-(2',3',5'-tri-O-acetyl-β-D-ribofuranosyl)-9H-purine 
• 98-80-6 phenylboronic acid 

Downstream Products

• 56489-66-8 2-Phenyl-6-thioinosine 
• 95962-88-2 2-Phenylnebularine 
• 37151-14-7 2-Phenyladenosine 
• 32447-14-6 2-Phenylinosine 
• 56489-65-7 6-chloro-2-phenyl-9-(β-D-ribofuranosyl)purine 

Relevant articles and documents

Synthetic Transformations of Transient Purinyl Radicals: Formation of Mono- and Diarylated and Heteroarylated Nucleosides

Photolysis of 2,6-dihalogenated purine nucleosides produced, through cleavage of the carbon-halogen bond, both purin-2-yl and purin-6-yl radicals (or caged radical pairs) which were intercepted by aromatic solvents such as benzene to produce 2-aryl- or 2,6-diarylpurine nucleosides.Heteroarylations and their selectivities involving pyrrole, thiophene, furan, and pyridine systems were als explored.In all cases, except for the "?-deficient" pyridine, the photoinduced heteroarylations were regiospecific and the products photostable.Photoinduced hydration of 2-substituted 6-chloropurine nucleosides provides an excellent approach for the synthesis of uncommon 2-substituted inosine analogues.High-field 13C NMR data suggest that the 2,6-disubstituted purine nucleosides prefer the anti conformation in solution.

A Convenient Method for the Synthesis of 2-Phenyl- and 2-Heteroarylpurine Nucleosides

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