Cas 71147-56-3,Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine

71147-56-3

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Basic information

Product Name: Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine
Synonyms: Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine
CAS NO:71147-56-3
Molecular Formula:
Molecular Weight: 755.175
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine(CAS DataBase Reference)
NIST Chemistry Reference: Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine(71147-56-3)
EPA Substance Registry System: Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine(71147-56-3)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 71147-56-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 71147-56-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,1,1,4 and 7 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 71147-56:
(7*7)+(6*1)+(5*1)+(4*4)+(3*7)+(2*5)+(1*6)=113
113 % 10 = 3
So 71147-56-3 is a valid CAS Registry Number.

71147-56-3Upstream product

71147-56-3Downstream Products

71147-56-3Relevant academic research and scientific papers

Synthesis of β-Bromo-Substituted Cu(II) Tetraphenylporphyrinates

Chizhova,Shinkarenko,Zav’yalov,Mamardashvili, N. Zh.

, p. 732 - 735 (2018/07/14)

Bromination reactions of Cu(II) 5,10,15,20-tetraphenylporphyrinate with N-bromosuccinimide in chloroform and chloroform–dimethylformamide mixture and complexation of 2-bromo-5,10,15,20-tetraphenylporphyrin and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with copper(II) acetate in dimethylformamide have been studied. Mono-, tetra-, and octabromo-substituted Cu(II) porphyrinates have been synthesized. Obtained compounds have been identified by electronic absorption spectroscopy, IR spectroscopy, mass spectrometry, and elemental analysis.

Complex formation of β-brominated tetraphenylporphyrins and metal exchange of their cadmium complexes with d-metal salts in dimethylformamide

Maltseva,Zvezdina,Chizhova,Mamardashvili, N. Zh.

, p. 102 - 109 (2016/03/12)

Complex formation of zinc and copper(II) acetates with tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in N,N-dimethylformamide has been studied. The rate constants determined in the study of the complex formation and the metal exchange reactions have been compared.

Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

Zvezdina,Mal'Tseva,Chizhova,Scheblykin,Mamardashvili

, p. 486 - 490 (2013/07/26)

The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)2) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

Spectral and complex-forming properties of ?-bromo-substituted porphyrins in N,N-dimethylformamide

Mal'tseva,Chizhova,Mamardashvili

, p. 1278 - 1283 (2012/11/07)

Contributions of structural and electronic effects to the reactivity and chromophore properties of tetrapyrrole macrocycles modified by bromine atoms were revealed on the basis of the kinetic data on the complex formation of 2-bromo-5,10,15,20-tetraphenyl

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