71173-67-6Relevant articles and documents
Preparation method of thioacetic acid geraniol ester
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Paragraph 0029-0065, (2019/09/13)
The invention relates to a preparation method of thioacetic acid geraniol ester. The preparation method comprises the following specific steps: (1) stirring geraniol and thioacetic acid in a dichloromethane solvent to carry out a reaction for 4-10 hours by taking pyridine as a catalyst, and after the reaction is ended, adjusting the pH value of the reaction solution to be neutral to obtain a neutral reaction solution; and (2) extracting the neutral reaction solution obtained in the step (1) by using an organic solvent, drying the obtained organic layer, carrying out filtering, concentrating the filtrate to obtain a crude product, and carrying out column chromatography on the crude product to obtain the thioacetic acid geraniol ester. Compared with the prior art, the preparation method disclosed by the invention is simple in preparation process, convenient in operation and high in yield; purity of the final product thioacetic acid geraniol ester is high; production cost is low; and themethod is suitable for industrial production.
Palladium-catalyzed synthesis of allylic thioacetates. A convenient access to allylic thiols
Divekar, Sunil,Safi, Mohamed,Soufiaoui, Mohamed,Sinou, Denis
, p. 4369 - 4376 (2007/10/03)
Palladium(0)-catalyzed alkylation of various allylic acetates and carbonates by potassium thioacetate allowed an easy access to allylic thioacetates in rather good yields. The reaction was regioselective with substitution at the less hindered side of the intermediate π-allyl system, and diastereoselective with net retention of configuration.