71186-63-5Relevant articles and documents
Enzymatic allylation of catechols
Zhang, Yixin,Liu, Wujun,Sohail, Muhammad,Wang, Xueying,Liu, Yuxue,Zhao, Zongbao K.
supporting information, p. 949 - 951 (2015/08/24)
Enzymatic allylation of catechols was realized via catechol O-methyltransferase (COMT) using an allylated S-adenosyl- L-methionine (allyl-SAM) analog, with relatively good chemoand regioselectivities. This new reaction offered an alternative procedure for allylation of catechols, which can be expanded as a biocatalytic allylation method in organic synthesis.
Synthesis of 2H-1,5-benzodioxepin and 2,5-dihydro-1,6-benzodioxocin derivatives via ring-closing metathesis reaction
Mamouni,Soukri,Lazar,Akssira,Guillaumet
, p. 2631 - 2633 (2007/10/03)
The synthesis of various 2H-1,5-benzodioxepin and 2,5-dihydro-1,6- benzodioxocin derivatives is described. The key step involves the construction of seven- and eight-membered rings via ring-closing metathesis reaction.
Total synthesis of (±)-Eusiderin K and (±)-Eusiderin J
Jing, Xiaobi,Gu, Wenxin,Bie, Pingyan,Ren, Xinfeng,Pan, Xinfu
, p. 861 - 867 (2007/10/03)
(±)-Eusiderin K and (±)-Eusiderin J were first synthesized from pyrogallol, in which the Claisen Rearrangement was used to afford two important C6-C3 units.
