71195-28-3

Upstream product

• 67-56-1 methanol 
• 3919-11-7 trans-Cyclohex-2-ene-1,4-dicarboxylic acid 
• 201230-82-2 carbon monoxide 
• 1165952-91-9 cyclohexa-1,3-diene 
• 19618-93-0 2-cyclohexene-1,4-dicarboxylic acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 100-21-0 terephthalic acid 
• 74-88-4 methyl iodide 
• 186581-53-3 diazomethane 

Downstream Products

• 131721-14-7 (Z)-6-[(1R,4R)-((1Z,4Z)-4-Deca-1,4-dienyl)-cyclohex-2-enyl]-hex-5-enoic acid 
• 131721-16-9 (Z)-5-[(1R,4R)-((1Z,4Z)-4-Deca-1,4-dienyl)-cyclohex-2-enyl]-pent-4-enoic acid 
• 131721-15-8 (5Z,8Z)-9-[(1R,4R)-((Z)-4-Hept-1-enyl)-cyclohex-2-enyl]-nona-5,8-dienoic acid 
• 131721-10-3 2-[(1S,4R)-((1Z,4Z)-4-Deca-1,4-dienyl)-cyclohex-2-enylmethoxy]-tetrahydro-pyran 
• 131721-17-0 (4Z,7Z)-8-[(1R,4R)-((Z)-4-Hept-1-enyl)-cyclohex-2-enyl]-octa-4,7-dienoic acid 
• 131721-11-4 2-[(1S,4R)-((Z)-4-Hept-1-enyl)-cyclohex-2-enylmethoxy]-tetrahydro-pyran 
• 131721-08-9 [(1S,4S)-4-(Tetrahydro-pyran-2-yloxymethyl)-cyclohex-2-enyl]-methanol 
• 131721-09-0 Triphenyl-[(1S,4S)-4-(tetrahydro-pyran-2-yloxymethyl)-cyclohex-2-enylmethyl]-phosphonium; iodide 
• 131721-12-5 [(1S,4R)-((1Z,4Z)-4-Deca-1,4-dienyl)-cyclohex-2-enylmethyl]-triphenyl-phosphonium; iodide 
• 131721-13-6 [(1S,4R)-((Z)-4-Hept-1-enyl)-cyclohex-2-enylmethyl]-triphenyl-phosphonium; iodide 
• 3919-11-7 trans-Cyclohex-2-ene-1,4-dicarboxylic acid 

Relevant academic research and scientific papers

Synthesis of rigidified arachidonic acid analogues

The synthesis of eight arachidonic acid analogues, rigidified by bridging the 7- and 10- or the 10-and 13-bis-allylic positions, is described.

Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2

A site-selective catalytic incorporation of multiple CO2 molecules into 1,3-dienes en route to adipic acids is described. This protocol is characterized by its mild conditions, excellent chemo- and regioselectivity and ease of execution under CO2 (1 atm), including the use of bulk butadiene and/or isoprene feedstocks.