713524-75-5

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 84501-28-0 2-hydroxy-5-t-butylisophthalaldehyde 

Downstream Products

• 946409-80-9 5-tert-butyl-1,3-diformyl-2-iodobenzene 
• 1424432-44-9 2,6-bis((4R,5R)-1-benzyl-4,5-diphenylimidazolidin-2-yl)-4-(tert-butyl)phenyl trifluoromethanesulfonate 
• 946409-81-0 1,4-bis[(4-tert-butyl-2-formylphenyl)ethynyl]-2,3-bis[(4-tert-butyl-2,6-diformylphenyl)ethynyl]benzene 
• 713524-71-1 trans-(4-tert-butyl-2,6-difolmylphenyl)chlorobis(triphenylphosphine)-palladium 

Relevant academic research and scientific papers

An N-C-N pincer palladium complex as an efficient catalyst precursor for the Heck reaction

The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140°C in the presence of 1 mol ppb of the pincer palladium complex [4-tert-butyl-2,6-bis{(3R,7aS)-2-phenylhexahydro-1H-pyrrolo[1,2-c] imidazole-1-on-3-yl}-phenyl]chloropall

Development of chiral pincer palladium complexes bearing a pyrroloimidazolone unit. Catalytic use for asymmetric Michael addition

Matrix presented. Novel pincer palladium complexes having chiral hexahydro-1H-pyrrolo[1,2-c]imidazolone groups were designed and prepared. Catalytic asymmetric Michael addition of isopropyl 2-cyanopropionate to ethyl vinyl ketone was catalyzed by the chiral pincer palladium complex to give isopropyl 2-cyano-2-methyl-5-oxoheptanoate with high enantioselectivity (up to 83% ee).

Syntheses and photophysical properties of boomerang-shaped Bis(dehydrobenzo[12]annulene) and trapezoid-shaped tris(dehydrobenzo[12] annulene)

A boomerang-shaped bis(dehydrobenzo[12]annulene) and a trapezoid-shaped tris(dehydrobenzo[12]annulene) were synthesized, and their ground- and excited-state properties were investigated. Copyright