7137-79-3 Usage
Molecular structure
A complex structure with multiple fused benzene and diazocine rings.
Explanation
The compound consists of a dibenzodiazocine core with various substituents, resulting in a complex molecular architecture.
Explanation
The compound is based on the dibenzodiazocine structure, which is a fused ring system consisting of two benzene rings and a diazocine ring.
Explanation
Due to its unique properties and structure, the compound may have potential uses in the development of pharmaceuticals or as an intermediate in industrial processes.
Explanation
The compound has four methyl groups (CH3) attached to the benzene rings, which can influence its chemical properties and reactivity.
Explanation
The diazocine ring is a six-membered ring with four nitrogen atoms, which is an essential part of the compound's structure and contributes to its unique properties.
Explanation
The fusion of multiple aromatic rings in the compound's structure contributes to its stability and may influence its chemical properties.
Explanation
The combination of the fused-ring structure and the substitution pattern results in unique properties that may be valuable for further studies and potential applications in drug discovery and development.
Dibenzodiazocine derivative
A chemical compound derived from the dibenzodiazocine ring system.
Potential applications
Pharmaceutical and industrial sectors.
Four methyl groups
The presence of four methyl groups attached to the benzene ring.
Nitrogen-containing diazocine ring
A key structural feature of the compound.
Fused-ring structure
The compound has multiple fused benzene and diazocine rings.
Substitution pattern
The arrangement of substituents on the benzene rings.
Unique properties
The compound exhibits distinct characteristics due to its structure and substitution pattern.
Check Digit Verification of cas no
The CAS Registry Mumber 7137-79-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,1,3 and 7 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 7137-79:
(6*7)+(5*1)+(4*3)+(3*7)+(2*7)+(1*9)=103
103 % 10 = 3
So 7137-79-3 is a valid CAS Registry Number.
InChI:InChI=1/C18H22N2/c1-13-5-7-17-15(9-13)11-19(3)18-8-6-14(2)10-16(18)12-20(17)4/h5-10H,11-12H2,1-4H3
7137-79-3Relevant academic research and scientific papers
Diiodomethane-mediated generation of n-aryliminium ions and subsequent [4 + 2] cycloadditions with olefins
Zhao, Yu-Quan,Tian, Jun-Jie,Ai, Chong-Ren,Wang, Xiao-Chen
, p. 2456 - 2465 (2020/03/11)
Herein, we report a method for in situ generation of N-aryliminium ions via reactions of N,N-dimethylanilines with diiodomethane. We used the method to prepare tetrahydroquinolines via one-pot three-component reactions between N,N-dimethylanilines, diiodomethane, and olefins. This transformation involves initial reaction of the aniline with diiodomethane to form an iodomethylammonium salt, which undergoes fragmentation accompanied by elimination of methyl iodide to give an N-aryliminium ion, which is trapped by the olefin via [4 + 2] cycloaddition to give the final product. This method for generating N-aryliminium ions requires neither a catalyst nor a strong oxidant, suggesting that it can be expected to find broad utility, especially for substrates that are sensitive to Lewis acids, transition metals, or strong oxidants.
PALLADIUM ASSISTED N-METHYL ACTIVATION OF p-SUBSTITUTED N,N-DIMETHYLANILINES
Sakakibara, Tsutomu,Hamakawa, Tomoko
, p. 1823 - 1824 (2007/10/02)
Intermediates in reaction of N,N-dimethylanilines with palladium(II) acetate were trapped by acetate ion or oxygen to give N-methyloxygenated and demethylated products, while the trapping by other anilines gave homo- and cross-coupling cyclodimers.The reactions proceed via radical cation formation induced by the palladium salt.
OXIDATIVE CYCLODIMERIZATION OF N,N-DIMETHYLANILINES. A NOVEL CARBON-CARBON BOND FORMATION BY PALLADIUM(II) ACETATE
Sakakibara, Tsutomu,Matsuyama, Haruhiko
, p. 1331 - 1334 (2007/10/02)
The reaction of N,N-dimethylanilines p-susbstituted by electrondonating groups with palladium(II) acetate in a mixed solvent of benzene and acetic acid gave cyclodimerized products, i.e. 5,6,11,12-tetrahydrodibenzodiazocine derivatives in good yields, via novel C-C bond formation, along with small amount of acetoxylated or demethylated products.Radical cation species was suggested as a cyclodimerization intermediate.
