71403-31-1

Basic information

• Product Name: (2-bromobenzyl)(2-bromophenyl)sulfane
• Synonyms: (2-bromobenzyl)(2-bromophenyl)sulfane
• CAS NO: 71403-31-1
• Molecular Weight: 358.096
• Mol File: 71403-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-bromobenzyl)(2-bromophenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-bromobenzyl)(2-bromophenyl)sulfane(71403-31-1)
• EPA Substance Registry System: (2-bromobenzyl)(2-bromophenyl)sulfane(71403-31-1)

Safety Data

• Hazardous Substances Data: 71403-31-1(Hazardous Substances Data)

Upstream product

• 19614-16-5 2-bromo-1-(methylsulfanyl)benzene 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 6320-02-1 o-bromothiophenol 

Downstream Products

• 343319-58-4 phenyl(1-(o-tolyl)ethyl)sulfane 
• 1221446-35-0 C₁₅H₁₂O₂S 
• 683278-24-2 C₁₅H₁₂O₄S 

Relevant articles and documents

Alkyl Sulfides as Promising Sulfur Sources: Metal-Free Synthesis of Aryl Alkyl Sulfides and Dialkyl Sulfides by Transalkylation of Simple Sulfides with Alkyl Halides

A site-selective metal-free dealkylative approach to synthesize aryl alkyl and symmetrical dialkyl sulfides has been developed. This procedure is convenient and has wide functional group tolerance giving rise to sulfides carrying various alkyl chains from simple alkyl sulfides and alkyl halides in good to excellent yields. This transalkylation proceeds by an ionic mechanism via sulfonium intermediates and it was proposed that dimethylacetamide (DMAC) may participate in part to promote the reaction.