71472-68-9Relevant academic research and scientific papers
Cationic cyclization of keto-epoxides mediated by zirconium(IV) tetrachloride: Diastereoselective synthesis of cis-decalinols
Goncalves, Sylvie,Nicolas, Marc,Maillos, Philippe,Baati, Rachid
experimental part, p. 8373 - 8382 (2011/11/14)
10-Methyl-cis-9-decalinols are important motifs in several natural products and key intermediates in total synthesis. Herein, we wish to describe a highly chemo- and diastereoselective cyclization of keto-epoxides leading to 10-methyl-cis-9-decalinols. Th
3-Methylcyclohex-2-enone Derivatives as Initiators of Cyclisation. Part 1. Introduction and Synthesis of 2-Substituted 3-methylcyclohex-2-enones
Amupitan, Joseph A.,Huq, Enamul,Mellor, Michael,Scovell, Edward G.,Sutherland, James K.
, p. 747 - 749 (2007/10/02)
A series of C-2 substituted 3-methylcyclohex-2-enones has been prepared using the Hagemann ester route.A new synthesis of these compounds has been developed which involves the alkylation of the N,N-diethylaminoethyl ether of 1-hydroxy-5-methylcyclohexa-1,5-diene.The cyclohexenones have been converted into the corresponding α,β-epoxyketones using alkaline hydrogen peroxide.
