87020-30-2Relevant articles and documents
Cationic cyclization of 2-alkenyl-1,3-dithiolanes: Diastereoselective synthesis of trans-decalins
Goncalves, Sylvie,Santoro, Stefano,Nicolas, Marc,Wagner, Alain,Maillos, Philippe,Himo, Fahmi,Baati, Rachid
, p. 3274 - 3285 (2011/06/25)
An unprecedented and highly diastereoselective 6-endo-trig cyclization of 2-alkenyl-1,3-dithiolanes has been developed yielding trans-decalins, an important scaffold present in numerous di- and triterpenes. The novelty of this 6-endo-trig cyclization stan