87020-30-2

Upstream product

• 917-64-6 methyl magnesium iodide 
• 64354-84-3 3-(3-methoxy-phenethyl)-2-methyl-4-oxo-cyclohex-2-enecarboxylic acid ethyl ester 
• 487-51-4 4-carbethoxy-3-methyl-2-cyclohexen-1-one 
• 40759-46-4 1-(2-methanesulfonyloxyethyl)-3-methoxybenzene 
• 2146-61-4 3-methoxyphenethyl bromide 
• 1292848-81-7 3-methoxy-2-[2-(3-methoxyphenyl)ethyl]cyclohex-2-en-1-one 
• 69629-57-8 2-[2-(3-Methoxy-phenyl)-acetyl]-cyclohexane-1,3-dione 

Downstream Products

• 1292848-59-9 6-[2-(3-methoxyphenyl)ethyl]-7-methyl-1,4-dithiaspiro[4.5]dec-6-ene 
• 123060-96-8 2-(2-m-methoxyphenylethyl)-1,3,3-trimethylcyclohexanol 
• 71472-68-9 1-[2-(3-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-one 
• 139006-73-8 2-(m-methoxyphenylethyl)-3,3-dimethylcyclohexan-1-one 

Relevant academic research and scientific papers

Cationic cyclization of 2-alkenyl-1,3-dithiolanes: Diastereoselective synthesis of trans-decalins

An unprecedented and highly diastereoselective 6-endo-trig cyclization of 2-alkenyl-1,3-dithiolanes has been developed yielding trans-decalins, an important scaffold present in numerous di- and triterpenes. The novelty of this 6-endo-trig cyclization stan

3-Methylcyclohex-2-enone Derivatives as Initiators of Cyclisation. Part 1. Introduction and Synthesis of 2-Substituted 3-methylcyclohex-2-enones

A series of C-2 substituted 3-methylcyclohex-2-enones has been prepared using the Hagemann ester route.A new synthesis of these compounds has been developed which involves the alkylation of the N,N-diethylaminoethyl ether of 1-hydroxy-5-methylcyclohexa-1,5-diene.The cyclohexenones have been converted into the corresponding α,β-epoxyketones using alkaline hydrogen peroxide.