715-61-7Relevant academic research and scientific papers
Unexpected distinction in reactivity of pentafluorobenzenesulfonyl halides toward organolithiums and organomagnesium halides
Bardin, Vadim V.,Maksimov, Alexander M.
, p. 731 - 737 (2017/10/16)
C6F5SO2Cl reacts with organolithiums and organomagnesium halides RM (R = Me, Bu, Ph; M = Li, MgX) to give mainly C6F5H and C6F5Cl. C6F5SO2Br and
Transition-metal-free synthesis of fluorinated arenes from perfluorinated arenes coupled with grignard reagents
Sun, Yunqiang,Sun, Hongjian,Jia, Jiong,Du, Aiqin,Li, Xiaoyan
supporting information, p. 1079 - 1081 (2014/03/21)
A simple method to obtain organofluorine compounds from perfluorinated arenes coupled with Grignard reagents in the absence of a transition-metal catalyst was reported. In particular, the perfluorinated arenes could react not only with aryl Grignard reagents but also with alkyl Grignard reagents in moderate to good yields.
