71500-16-8Relevant articles and documents
High temperature chemistry of the gaseous ruthenium fluorides
Hildenbrand, D. L.,Lau, K. H.
, p. 5825 - 5828 (1988)
Mass spectrometry was used to identify and to thermochemically characterize the gaseous fluorides RuF4, RuF3, RuF2, and RuF generated by fluorination of Ru powder in a platinum effusion cell.Reaction enthalpies and bond dissociation energies were derived from equilibrium measurements involving these species, yielding the following results in kJ mol-1: Ddeg(F3Ru-F) = 361; Ddeg(F2Ru-F) = 339; Ddeg(FRu-F) = 464; and Ddeg(Ru-F) = 402.The results show that the + 4 oxidation state dominates the high temperature chemistry of the Ru-F system.Results are compared with the properties of the neighboring Mo-F system.