71506-76-8Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling reaction of azides with isocyanides
Zhang, Zhen,Li, Zongyang,Fu, Bin,Zhang, Zhenhua
supporting information, p. 16312 - 16315 (2015/11/16)
An efficient palladium-catalyzed cross-coupling reaction of azides with isocyanides is developed, providing a general synthetic route to unsymmetric carbodiimides with excellent yields. This method shows a broad substrate scope, including not only aryl azides, but also unactivated benzyl and alkyl azides. Furthermore, from readily available substrates, Pd-catalyzed coupling with a tandem amine insertion cascade to obtain unsymmetric trisubstituted guanidines has been achieved in a one-pot fashion.
A mild, efficient approach for the synthesis of 1,5-disubstituted hydantoins
Olimpieri, Francesca,Bellucci, Maria Cristina,Volonterio, Alessandro,Zanda, Mateo
scheme or table, p. 6179 - 6188 (2010/03/04)
An efficient and straightforward two-step procedure for the synthesis of N-1 alkyl/aryl-substituted hydantoins was developed, starting from easily available starting materials. The procedure envisages a highly reglospecific domino condensation/aza-Michael
