71545-99-8

Basic information

• Product Name: 1(2H)-Naphthalenone, 4-bromo-3,4-dihydro-
• CAS NO: 71545-99-8
• Molecular Formula: C10H9BrO
• Molecular Weight: 225.085
• Mol File: 71545-99-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1(2H)-Naphthalenone, 4-bromo-3,4-dihydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 1(2H)-Naphthalenone, 4-bromo-3,4-dihydro-(71545-99-8)
• EPA Substance Registry System: 1(2H)-Naphthalenone, 4-bromo-3,4-dihydro-(71545-99-8)

Safety Data

• Hazardous Substances Data: 71545-99-8(Hazardous Substances Data)

Upstream product

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 

Downstream Products

• 5328-01-8 1-ethoxynaphthalene 
• 60951-03-3 1-(hexyloxy)naphthalene 
• 64833-49-4 4-amino-3,4-dihydro-2H-naphthalen-1-one 
• 1313021-93-0 tert-butyl N-(4-oxo-1,2,3,4-tetrahydro-1-naphthalenyl)carbamate 
• 1313022-03-5 4-[2-cyclohexenyl(2-naphthylmethyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 1313022-01-3 4-[2-cyclohexenyl(4-methylbenzyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 1313022-00-2 4-[benzyl(2-cyclohexenyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 1313021-99-6 4-[allyl(2-cyclohexenyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 1313021-98-5 4-[2-cyclohexenyl(methyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 1313021-94-1 4-(2-cyclohexenylamino)-1,2,3,4-tetrahydro-1-naphthalenone 
• 1106767-91-2 4-[benzyl(methyl)amino]-1,2,3,4-tetrahydro-1-naphthalenone 
• 2216-69-5 1-Methoxynaphthalene 
• 20900-19-0 1-n-butoxynaphthalene 
• 20009-27-2 1-isopropoxynaphthalene 

Relevant articles and documents

Environmentally benign electrophilic and radical bromination 'on water': H2O2-HBr system versus N-bromosuccinimide

A H2O2-HBr system and N-bromosuccinimide in an aqueous medium were used as a 'green' approach to electrophilic and radical bromination. Several activated and less activated aromatic molecules, phenylsubstituted ketones and styrene were efficiently brominated 'on water' using both systems at ambient temperature and without an added metal or acid catalyst, whereas various non-activated toluenes were functionalized at the benzyl position in the presence of visible light as a radical activator. A comparison of reactivity and selectivity of both brominating systems reveals the H2O2-HBr system to be more reactive than NBS for benzyl bromination and for the bromination of ketones, while for electrophilic aromatic substitution of methoxy-substituted tetralone it was higher for NBS. Also, higher yields of brominated aromatics were observed when using H2O2-HBr 'on water'. Bromination of styrene reveals that not just the structure of the brominating reagent but the reaction conditions: amount of water, organic solvent, stirring rate and interface structure, play a key role in defining the outcome of bromination (dibromination vs bromohydroxylation). In addition, mild reaction conditions, a straightforward isolation procedure, inexpensive reagents and a lower environment impact make aqueous brominating methods a possible alternative to other reported brominating protocols.