716329-02-1

Basic information

• Product Name: methyl 2-acetamido-4-azido-3-O-benzoyl-2,4,6-trideoxy-α-D-galactopyranoside
• Synonyms: methyl 2-acetamido-4-azido-3-O-benzoyl-2,4,6-trideoxy-α-D-galactopyranoside
• CAS NO: 716329-02-1
• Molecular Weight: 348.359
• Mol File: 716329-02-1.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-acetamido-4-azido-3-O-benzoyl-2,4,6-trideoxy-α-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-acetamido-4-azido-3-O-benzoyl-2,4,6-trideoxy-α-D-galactopyranoside(716329-02-1)
• EPA Substance Registry System: methyl 2-acetamido-4-azido-3-O-benzoyl-2,4,6-trideoxy-α-D-galactopyranoside(716329-02-1)

Safety Data

• Hazardous Substances Data: 716329-02-1(Hazardous Substances Data)

Upstream product

• 87236-56-4 methyl 2-acetamido-6-bromo-2,6-dideoxy-α-D-glucopyranoside 
• 50286-18-5 methyl 2-acetamido-2,6-dideoxy-α-D-glucopyranoside 
• 716329-01-0 methyl 2-acetamido-3-O-benzoyl-2,6-dideoxy-α-D-glucopyranoside 

Relevant articles and documents

An efficient synthesis of derivatives of 2-acetamido-4-amino-2,4,6- trideoxy-D-galactopyranose

Methyl 2-acetamido-4-amino-2,4,6-trideoxy-α-D-galactopyranoside (10) was synthesized from D-glucosamine hydrochloride in eight steps in an overall yield of 31%. Key steps include the selective benzoylation at O-3 of methyl 2-acetamido-2,6-dideoxy-α-D-glucopyranoside in 89% yield and the subsequent Mitsunobu reaction using diphenylphosphoryl azide as the azide source which proceeded in 92% yield. Di- and mono-benzyloxycarbonyl derivatives of 10 were also prepared. Copyright