716349-05-2Relevant articles and documents
A novel 1,2-migration of acyloxy, phosphatyloxy, and sulfonyloxy groups in allenes: Efficient synthesis of tri- and tetrasubstituted furans
Sromek, Anna W.,Kel'in, Alexander V.,Gevorgyan, Vladimir
, p. 2280 - 2282 (2004)
Heading south: The 1,2-migration of the acyloxy, phosphatyloxy, and sulfonyloxy groups in allenyl systems has been discovered. This migration, combined with the transition-metal-catalyzed cycloisomerization reaction, leads to the efficient synthesis of tr
Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: Efficient synthesis of heterocycles via cascade migration/cycloisomerization approach
Schwier, Todd,Sromek, Anna W.,Yap, Dahrika M. L.,Chernyak, Dmitri,Gevorgyan, Vladimir
, p. 9868 - 9878 (2008/03/12)
A set of cycloisomerization methodologies of alkynyl ketones and imines with concurrent acyloxy, phosphatyloxy, or sulfonyloxy group migration, which allow for the efficient synthesis of multisubstituted furans and N-fused heterocycles, has been developed