71653-45-7Relevant academic research and scientific papers
From ketones to esters by a Cu-catalyzed highly selective C(CO)-C(alkyl) bond cleavage: Aerobic oxidation and oxygenation with air
Huang, Xiaoqiang,Li, Xinyao,Zou, Miancheng,Song, Song,Tang, Conghui,Yuan, Yizhi,Jiao, Ning
supporting information, p. 14858 - 14865 (2014/12/11)
The Cu-catalyzed aerobic oxidative esterification of simple ketones via C-C bond cleavage has been developed. Varieties of common ketones, even inactive aryl long-chain alkyl ketones, are selectively converted into esters. The reaction tolerates a wide range of alcohols, including primary and secondary alcohols, chiral alcohols with retention of the configuration, electron-deficient phenols, as well as various natural alcohols. The usage of inexpensive copper catalyst, broad substrate scope, and neutral and open air conditions make this protocol very practical. 18O labeling experiments reveal that oxygenation occurs during this transformation. Preliminary mechanism studies indicate that two novel pathways are mainly involved in this process. (Chemical Equation Presented)
HYDROLYSIS OF N-METHYLNICOTINYL AND N-METHYLISONICOTINYL ESTERS AND SOME n-PARTICIPATING DERIVATIVES UNDER MICELLAR CONDITIONS
Jursic, Branko,Ladika, Mladen,Sunko, Dionis E.
, p. 1955 - 1968 (2007/10/02)
Hydrolysis rate of two types of compounds, A and B were studied in the presence of variable concentrations of an anionic surfactant (sodium dodecylsulfate, SDS).Class A of compounds consists of substances which hydrolyze by the SN1 mechanism and which are
