71660-53-2Relevant academic research and scientific papers
REACTIONS OF RUTHENIUM TRIPHENYLPHOSPHINE COMPLEXES WITH DIAZADIENES II. REACTIONS OF RuH2(PPh3)4 AND RuH4(PPh3)3
Chaudret, B.,Poilblanc, R.
, p. 115 - 122 (2007/10/02)
The reactions between RuH2(PPh3)4 or RuH4(PPh3)3 and 1,2-di(isopropylimino)ethane (DAD-A), 2,3-di(phenylimino)butane DAD-C) and 1,2-di(p-methoxyphenylimino)ethane (DAD-D) in toluene produce symmetrical trans dihydrido complexes.However the product obtained from DAD-C is difficult to isolate, and attempts to prepare it in alkanes led to the isolation of hexa-coordinate cis-dihydrido and pentacoordinate cis-dihydrido complexes in which the diazadiene is coordinated only through one end.A scheme showing the proposed reaction sequence is presented.
Reactions of Ruthenium Triphenylphosphine Complexes with Diazadienes. Part 1. Reactions of and and Disproportionation of a Hydridochloro-complex
Chaudret, Bruno,Poilblanc, Rene
, p. 539 - 544 (2007/10/02)
The reactions between and half or one equivalent of a diazadiene (dad) give respectively molecular and ionic binuclear triply chloro-bridged complexes, and Cl which can also be obtained as its BPh4 salt.The compound reacts with diazadienes to produce , which disproportionates in polar solvents to give a hydrido- and a dichloro-compound and reacts with water to give a chlorodihydroxo-bridged hydrido-species, .
