71672-07-6

Upstream product

• 100-39-0 benzyl bromide 
• 5328-50-7 D-cellobiose octaacetate 
• 18464-08-9 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-glucopyranose 
• 57764-18-8 benzyl hepta-O-acetyl-α,β-cellobioside 
• 104992-64-5 methyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside 
• 113409-92-0 C₄₀H₄₀O₆S 
• 30760-09-9 methyl 1-deoxy-1-thio-β-D-glucopyranoside 
• 13350-45-3 methyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 67831-42-9 benzyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 10343-13-2 benzyl-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 100-51-6 benzyl alcohol 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 57783-66-1 benzyl 4,6-O-benzylidene-2,3-tri-O-benzyl-β-D-glucopyranoside 

Downstream Products

• 108811-21-8 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→4)-2,3,6-tri-O-benzyl-α-D-glucopyranose 
• 108811-27-4 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1→4)-2,3,6-tri-O-benzyl-β-D-glucopyranose 
• 108811-21-8 2,3,6-tri-O-benzyl-4-O-(2′,3′,4′,6′-tetra-O-benzyl-α-D-glucopyranosyl)-D-glucopyranoside 

Relevant academic research and scientific papers

Regioselective removal of the anomeric O-benzyl from differentially protected carbohydrates

A mild, regioselective deprotection of the anomeric O-benzyl from multi-functionally protected carbohydrates via catalytic transfer hydrogenation is described. The protocol is tolerant of O-benzyl and O-benzylidene protections at non-anomeric positions, g

Dehydrative glycosylation by diethylaminosulfur trifluoride (DAST) - tin(II) trifluoromethanesulfonate-tetrabutylammonium perchlorate - triethylamine system

Dehydrative glycosylation using 2,3,4,6-tetra-O-benzyl-D-glucopyranose was carried out by the use of a condensing reagent system composed of diethylaminosulfur trifluoride (DAST), tin(II) triflate, tetrabutylammonium perchlorate, and triethylamine. Using this system, two tetrasaccharides, O- a-D-glucopyranosyl-(1→4)-O-α-D-glucopyranosyl-(1→3)-Oα-D-glucopyranosyl- (1→4)-D-glucopyranose and O-a-D-glucopyranosyl-(1→3)-O-α-D- glucopyranosyl-(1→4)-O-α-D-glucopyranosyl-(1→4)-D-glucopyranose, were synthesized.

SULFENATE ESTERS AS GLYCOSYL ACCEPTORS: A NOVEL APPROACH TO O-GLYCOSIDES FROM THIOGLYCOSIDES AND SULFENATE ESTERS

The reactions of thioglycosides and sulfenate esters were effected in the presence of Lewis acid to give corresponding O-glycosides.The stereoselectivity was highly dependent on the solvent.