717-41-9Relevant academic research and scientific papers
Construction of Chiral 1,3-Diamines through Rhodium-Catalyzed Asymmetric Arylation of Cyclic N-Sulfonyl Imines
Wu, Chun-Yan,Xu, Ming-Hua
supporting information, p. 5035 - 5039 (2019/07/03)
A rhodium/sulfur-olefin complex catalyzed asymmetric 1,2-addition of arylboronic acids to six-membered 1,2,6-thiadiazinane 1,1-dioxide-type cyclic imines to access highly optically active sulfamides (95-99% ee) has been developed. By taking advantage of t
Organometallics in Carbon-Carbon Bond Formation in 1,2,6-Thiadiazine 1,1-Dioxides
Wang, Liv Ragna Rohde,Benneche, Tore,Undheim, Kjell
, p. 726 - 732 (2007/10/02)
Carbon substituents have been introduced exclusively into the electrophilic 5-position in 1,2,6-thiadiazine 1,1-dioxides by 1,1-adduct formation with organomagnesium reagents followed by reoxidation by manganese dioxide to the conjugated, 5-substituted heterocycle.Pd(II)-catalyzed coupling reactions between organostannanes and the 4-bromo of 4-iodo derivatives have been used for the introduction of a 4-carbon substituent.Methods for chlorination, bromination or iodination in the 4-position are described.
