71700-50-0Relevant articles and documents
Oxidative Cleavage of Silyl Ethers by an Oxoammonium Salt
Loman, Jacob J.,Pistritto, Vincent A.,Kelly, Christopher B.,Leadbeater, Nicholas E.
, p. 2372 - 2377 (2016/09/28)
A method for the oxidative cleavage of silyl ethers to their corresponding carbonyl species mediated by an oxoammonium salt is described. The resulting aldehydes and ketones are obtained under mild reaction conditions with no observed overoxidation. For robust substrates, heating to reflux temperatures significantly reduces the reaction time.
Facile and convenient method of deuterium gas generation using a Pd/C-catalyzed H2-D2 exchange reaction and itsapplication to synthesis of deuterium-labeled compounds
Kurita, Takanori,Aoki, Fumiyo,Mizumoto, Takuto,Maejima, Toshihide,Esaki, Hiroyoshi,Maegawa, Tomohiro,Monguchi, Yasunari,Sajiki, Hironao
supporting information; experimental part, p. 3371 - 3379 (2009/04/10)
The Pd/C-catalyzed H2-D2 exchange reaction using a H2-D2O combination provided a general, efficient and environmentally friendly route for the preparation of deuterium gas (D 2). H2 sealed
An Effective Approach for the Silylation of Hydroxyl Compounds in Room Temperature Ionic Liquids
Xu, Zhen-Yuan,Xu, Dan-Qian,Liu, Bao-You,Luo, Shu-Ping
, p. 4143 - 4149 (2007/10/03)
The room temperature ionic liquid (RTIL) 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMImPF6) is used as a "green" recyclable alternative to conventional solvents for the silylation of a series of hydroxyl compounds (alcohols and phenols
