71738-68-6Relevant academic research and scientific papers
2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.
Hill, David R,Hsiao, Chi-Nung,Kurukulasuriya, Ravi,Wittenberger, Steven J
, p. 111 - 113 (2002)
[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.
On the two-component microwave-mediated reaction of isonitriles with carboxylic acids: Regarding alleged formimidate carboxylate mixed anhydrides
Li, Xuechen,Yuan, Yu,Berkowitz, William F.,Todaro, Louis J.,Danishefsky, Samuel J.
supporting information; experimental part, p. 13222 - 13224 (2009/02/06)
Microwave induced two-component coupling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides. The formimidate carboxylate mixed anhydride (FCMA) is proposed as the reactive intermediate, which undergoes 1,3-O→N acyl tr
A simple and convenient synthesis of N-formyl amino acid esters under mild conditions
Duczek,Deutsch,Vieth,Niclas
, p. 37 - 38 (2007/10/03)
A variety of amino acid ester hydrochlorides react with cyanomethyl formate at room temperature to give the N-formyl amino acid esters in good yields and without racemization.
