71796-68-4Relevant academic research and scientific papers
Oxidative rearrangement of 2-alkoxy-3,4-dihydro-2H-pyrans: stereocontrolled synthesis of 4,5-cis-disubstituted tetrahydrofuranones including whisky and cognac lactones and crobarbatic acid
Armstrong, Alan,Ashraff, Cassim,Chung, Hunsuk,Murtagh, Lorraine
experimental part, p. 4490 - 4504 (2009/10/09)
Oxidation of 2-alkoxy-3,4-dihydro-2H-pyrans 3 with dimethyldioxirane or MTO/urea-H2O2 followed by Jones oxidation leads to rearrangement and stereocontrolled formation of 4,5-cis-disubstituted tetrahydrofuranones. The method is applied to the synthesis of the whisky lactone 9, cognac lactone 10 and crobarbatic acid 17.
LANTHANIDE CATALYSIS OF CYCLOADDITIONS OF HETERODIENES WITH ENOL ETHERS
Danishefsky, Samuel,Bednarski, Mark
, p. 721 - 724 (2007/10/02)
The cycloadditions of enol ethers with α,β-unsaturated aldehydes is catalysed by Yb(fod)3.
