7199-98-6Relevant articles and documents
Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters
Garrais, Solange,Turkington, Jennifer,Goldring, William P.D.
experimental part, p. 8418 - 8427 (2009/12/26)
The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.