54981-67-8Relevant academic research and scientific papers
In situ alcohol oxidation-Wittig reactions
Wei, Xudong,Taylor, Richard J. K.
, p. 3815 - 3818 (1998)
Allytic, propargylic and benzylic alcohols can be oxidised with activated manganese dioxide in the presence of stabilised Wittig reagents to generate α, β-unsaturated esters directly. This simple procedure, which can also be utilised with diols to give do
Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters
Garrais, Solange,Turkington, Jennifer,Goldring, William P.D.
experimental part, p. 8418 - 8427 (2009/12/26)
The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.
